The step periodicity of GaAs vicinal surfaces, grown by molecular beam
epitaxy (MBE) was studied for a large range of misorientation (0.2 de
grees to 2 degrees towards [111]) using ex-situ atomic force microscop
y (AFM) under dry nitrogen gas. After growth, the statistical distribu
tion of the terrace width and the correlation length along the steps w
ere consistent with a thermodynamic equilibrium model taking into acco
unt an AL(-2) step-step interaction. These observations are qualitativ
ely similar to Si and metals after thermal annealing but, in addition
to elastic interaction, the dipole-dipole contribution has to be consi
dered in order to explain the large value of the coefficient A (A(Ga)
= 1.5 eV Angstrom) deduced for the force coefficient between the galli
um terminated steps. Step bunching occurred for highly Si-doped GaAs g
rowth and we discuss the best method for carrying out the measurements
in order to determine the step-step interaction.