Using planar laser induced fluorescence we have measured the ON concen
tration profiles outside a Pt catalyst at 1, 5, and 10 torr. The catal
yst was heated to 1300 K in a stagnation point flow consisting of 10%
hydrogen and 90% oxygen directed onto the surface. The measurements we
re compared to a model describing a laminar stagnation point how inclu
ding a detailed mechanism with elementary reactions in order to descri
be both the gas phase and surface reactions. The simulation shows that
the detected OW was not produced by gas phase reactions. Instead it i
s formed on the surface by H + O recombination, and a small percentage
of it desorbs and diffuses out from the catalyst. At 1 torr the form
of the ON gradient outside the catalyst was found to be determined sol
ely by diffusion and convection. At 5 and 10 torr gas phase reactions
also had to be included to correctly describe the shape of the OH conc
entration gradient. The dominant gas phase reaction is removal of OH m
olecules through reaction with hydrogen. (C) 1998 Academic Press.