NICKEL-BIPYRIDINE CATALYZED ELECTROSYNTHESIS OF KETONES FROM ORGANIC HALIDES AND CARBON-MONOXIDE - KINETIC AND MECHANISTIC INVESTIGATIONS

Authors
OCAFRAIN M DOLHEM E NEDELEC JY TROUPEL M
Citation
M. Ocafrain et al., NICKEL-BIPYRIDINE CATALYZED ELECTROSYNTHESIS OF KETONES FROM ORGANIC HALIDES AND CARBON-MONOXIDE - KINETIC AND MECHANISTIC INVESTIGATIONS, Journal of organometallic chemistry, 571(1), 1998, pp. 37-42
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
571
Issue
1
Year of publication
1998
Pages
37 - 42
Database
ISI
SICI code
0022-328X(1998)571:1<37:NCEOKF>2.0.ZU;2-3
Abstract
The reactivity of zerovalent nickel-2,2'-bipyridine complexes towards carbon monoxide and organic halides was investigated by electroanalyti cal methods. The kinetic data obtained allow us to propose two pathway s leading to the formation of an acylnickel complex by electroreductio n of Nibpy(2+) in the presence of both CO and a halocarbon. (C) 1998 E lsevier Science S.A. All rights reserved.