F-19 NMR-SPECTROSCOPY OF POLYHALONAPHTHALENES - PART IV - HALEX REACTIONS OF POLYCHLOROQUINOLINES

Authors
MATTHEWS RS
Citation
Rs. Matthews, F-19 NMR-SPECTROSCOPY OF POLYHALONAPHTHALENES - PART IV - HALEX REACTIONS OF POLYCHLOROQUINOLINES, Journal of fluorine chemistry, 91(2), 1998, pp. 203-205
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of fluorine chemistry → ACNP
ISSN journal
00221139
Volume
91
Issue
2
Year of publication
1998
Pages
203 - 205
Database
ISI
SICI code
0022-1139(1998)91:2<203:FNOP-P>2.0.ZU;2-F
Abstract
Nucleophilic fluoride dechlorination of four starting materials (5,6,7 ,8-tetrachloro-, 3,5,6,7,8-pentachloro-, 4,7-dichloro-, 2,3,4,5,6,7,8- heptachloro-quinoline) led to the preparation of thirteen new polychlo ropolyfluoroquinolines via reaction with caesium fluoride in DMSO at 1 00 degrees C. The product from the perchloroquinoline was an inseparab le mixture of C9Cl7-nFnN where n is 1-3. These products were studied i n the NMR tube. (C) 1998 Elsevier Science S.A. All rights reserved.