AN EASY AND EFFICIENT METHOD FOR OXIDATION OF ALCOHOLS AND AROMATIC-AMINES TO THE CORRESPONDING CARBONYL AND AZO-COMPOUNDS UNDER NONAQUEOUSAND NEUTRAL CONDITIONS

Authors
HAJIPOUR AR MAHBOOBKHAH N
Citation
Ar. Hajipour et N. Mahboobkhah, AN EASY AND EFFICIENT METHOD FOR OXIDATION OF ALCOHOLS AND AROMATIC-AMINES TO THE CORRESPONDING CARBONYL AND AZO-COMPOUNDS UNDER NONAQUEOUSAND NEUTRAL CONDITIONS, Indian journal of chemistry. Sect. B: organic chemistry, including medical chemistry, 37(3), 1998, pp. 285-287
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Indian journal of chemistry. Sect. B: organic chemistry, including medical chemistry → ACNP
ISSN journal
03764699
Volume
37
Issue
3
Year of publication
1998
Pages
285 - 287
Database
ISI
SICI code
0376-4699(1998)37:3<285:AEAEMF>2.0.ZU;2-S
Abstract
1-Benzyl-1-aza-4-azoniabicyclo[2.2.2]octane periodate 1, readily prepa red as an orange solid from commercially available 1,4-diazobicyclo[2. 2.2]octane, is useful for oxidation in anhydrous conditions. The reage nt converts alcohols to the corresponding carbonyl compounds, alpha-hy droxy ketones to diketones, and aromatic amines to azo compounds, in t he excellent yields. The reagent is ineffective in oxidising double bo nds, aldehydes and ketones.