The two-dimensional inviscid refraction of a shock wave at an oblique
contact discontinuity is self-similar; i.e. it depends only upon the v
ariables xi = x/t, eta = y/t. We transform the compressible Euler equa
tions into the self-similar (xi,eta) coordinates and solve the resulti
ng boundary-value problem by an implicit equilibrium flux method. We p
resent results for strong shock (M greater than or equal to 10 where M
is the incident shock Mach number) interactions with an oblique conta
ct discontinuity separating an inert gas from a gas which exhibits hig
h-temperature gas chemistry effects. To model high-temperature effects
we employ Lighthill's ideal dissociating gas (IDG) model. Comparison
between the frozen and equilibrium limits, both of which are self-simi
lar, indicate large changes in peak density and temperatures. Signific
ant differences in the overall flow pattern between the frozen and equ
ilibrium limits are observed for interfaces with low negative Atwood r
atio and high positive Atwood ratio. Results from a local analysis are
presented when the shock refraction is regular. The critical angle at
which the transition from regular to irregular refraction occurs is s
lightly larger for the equilibrium chemistry case.