Ca. Mccammon et al., FERRIC IRON CONTENT OF MINERAL INCLUSIONS IN DIAMONDS FROM GEORGE CREEK, COLORADO DETERMINED USING MOSSBAUER-SPECTROSCOPY, Contributions to Mineralogy and Petrology, 133(1-2), 1998, pp. 30-37
The Mossbauer milliprobe allows the determination of Fe3+/Sigma Fe in
samples as small as 50 mu m. For the first time this technique is appl
ied to a suite of diamonds of eclogitic paragenesis, where three garne
t and five clinopyroxene inclusions in diamonds from George Creek, Col
orado have been analysed. For garnet Fe3+/Sigma Fe ranges from 0-7%, w
hile values for clinopyroxene range from 8-14%. These results are cons
istent with the low oxygen fugacity conditions implied by the presence
of the inclusions in diamond.