J. Novakova, PLATINUM, PALLADIUM AND RHODIUM CLUSTERS IN ALKALI-X AND ALKALI-Y ZEOLITES - PREPARATION AND CATALYTIC ACTIVITY, Collection of Czechoslovak Chemical Communications, 63(11), 1998, pp. 1839-1850
Pt, Pd and Ph ammine cations partially ion-exchanged for alkali ions o
f X and Y zeolites were decomposed in vacuum to metallic clusters embe
dded in cavities. The course of the parent ammine decomposition as wel
l as the CO + NO reaction after the deammination to metallic clusters
were compared for the individual metals. The effects of the respective
metals as well as as those of the zeolitic matrices are discussed.