MODIFICATION OF SOME OXIDES BY ORGANIC AND ORGANOSILICON COMPOUNDS

Citation
Vm. Gunko et al., MODIFICATION OF SOME OXIDES BY ORGANIC AND ORGANOSILICON COMPOUNDS, Journal of adhesion science and technology, 11(5), 1997, pp. 627-653
Citations number
51
Categorie Soggetti
Engineering, Chemical","Material Science",Mechanics
ISSN journal
01694243
Volume
11
Issue
5
Year of publication
1997
Pages
627 - 653
Database
ISI
SICI code
0169-4243(1997)11:5<627:MOSOBO>2.0.ZU;2-7
Abstract
Highly dispersed oxides SiO2, TiO2, ZnO, and TiO2/SiO2 modified by org anic [di(ethylene glycol), glycerol, butanol, and methanol] and organo silicon (3-aminopropyltriethoxysilane, hexamethyldisilazane, methacryl oyloxymethylenemethyl diethoxysilane, and blend of methylcyclosiloxane s) compounds were studied by IR spectroscopy and quantum chemical ab i nitio and semi-empirical methods. Unmodified and modified oxides were tested as additives in ethyl cellulose and nitrocellulose coatings for improvement of their adhesion properties and light and corrosion resi stance. The results obtained show the possibility of improving these p roperties.