THE PERMEATION OF BINARY GAS-MIXTURES THROUGH SUPPORT STRUCTURES OF COMPOSITE MEMBRANES

The dusty gas model (DGM) is used to describe transport of binary gas mixtures through porous membrane supports to quantify the resistance t owards permeation. The model equations account for three different tra nsport mechanisms for the permeating components: conventional viscous pore flow, Knudsen diffusion, and binary diffusion. Experimental data obtained with the uncoated membrane supports are used to determine the morphological parameters needed in the DGM equations. Flat sheet and hollow fiber membrane supports are characterized by the permeation of a TCE/nitrogen vapor. The DGM shows an excellent fit to experimental d ata when the asymmetric structure of the membrane supports is taken in to account, but the morphological parameters cannot necessarily be rel ated to precise physical structure parameters such as pore size, poros ity, and tortuosity. The DGM works well even when the membrane support s are modeled as a single homogenous structure. The membrane supports exhibit different resistances towards the various transport mechanisms that occur within the porous support and the resistances vary with pr ocess conditions so that support optimization is not straightforward. With the analysis presented in this paper and transport equations spec ific to the dense coating and module geometries, the influence of the support layer on gas or vapor separation can be quantified. (C) 1998 E lsevier Science B.V. All rights reserved.