V. Pamukchieva et al., DC ELECTRICAL-CONDUCTIVITY IN GEXSB40-XS60 GLASSES AND THIN-FILMS, Semiconductor science and technology (Print), 13(11), 1998, pp. 1309-1312
DC electrical conductivity for bulk and thin-film samples of the GexSb
40-xS60 chalcogenide glass system was measured in the temperature rang
e 293-430 K. The activation energy Delta E and the pre-exponential fac
tor delta(0) have been determined. Values of delta(0) suggest differen
t mechanisms of conductivity in bulk glasses and in thin films. For ai
l compositional dependences a peculiarity was observed in the region w
ith an average coordination number Z similar to 2.67 which can be asso
ciated with a topological phase transition from a 2D to a 3D structure
.