In this work the optical properties of Yb3+ ions in LiNbO3 crystals ar
e studied as a function of temperature from 15 K to room temperature.
The population of the upper Stark levels in each state increases with
temperature and subsequently thermal bands appear in the absorption an
d fluorescence spectra. The intensity of a thermally activated absorpt
ion band fits well the Boltzmann profile. Efficient anti-Stokes photol
uminescence is observed when pumping transitions starting from the exc
ited Stark levels of the F-2(7/2) state. An increase of the decay time
versus temperature is observed in the case of moderate Yb3+ concentra
tion. It is related to a luminescence trapping mechanism since a diffe
rent behaviour is observed for less doped samples. (C) 1998 Elsevier S
cience B.V. All rights reserved.