Reflectance spectra from the surface of Mars collected by instruments
such as the imaging spectrometer (ISM) onboard the 1988 Soviet Phobos
2 spacecraft exhibit strong 3 mu m absorption features that have long
been attributed to hydrated materials on the Martian surface. This int
erpretation is consistent with a series of chemical weathering models
suggesting an abundance of palagonites, clays, and other hydrated mine
ral phases in the Martian fines. Little work, however, has been done t
o constrain the actual water content of the Martian surface materials.
New laboratory data presented here show that the ISM spectra are cons
istent with up to 4% water by weight and that the deep hydration featu
res observed in the spacecraft data could be due to less than 0.5% wat
er if the hydrated phases are present in the form of grain coatings. T
hese results are consistent with the somewhat uncertain in situ measur
ements obtained by the Viking landers which yielded approximately 2 wt
% water from samples heated to 500 degrees C. On the basis of this wo
rk, we expect the TEGA instrument on the Mars '98 lander to find less
than 4% adsorbed or bound water in the upper few centimeters of the Ma
rtian soil.