EFFECT OF FLUCTUATIONS ON THE FREEZING OF A COLLOIDAL SUSPENSION IN AN EXTERNAL PERIODIC POTENTIAL

Citation
J. Chakrabarti et S. Sinha, EFFECT OF FLUCTUATIONS ON THE FREEZING OF A COLLOIDAL SUSPENSION IN AN EXTERNAL PERIODIC POTENTIAL, Journal de physique. II, 7(5), 1997, pp. 729-741
Citations number
16
Categorie Soggetti
Physics, Atomic, Molecular & Chemical",Mechanics
Journal title
ISSN journal
11554312
Volume
7
Issue
5
Year of publication
1997
Pages
729 - 741
Database
ISI
SICI code
1155-4312(1997)7:5<729:EOFOTF>2.0.ZU;2-T
Abstract
We incorporate the effects of fluctuations in a density functional ana lysis of the freezing of a colloidal liquid in the presence of an exte rnal potential generated by interfering laser beams. A mean-field trea tment, using a density functional theory, predicts that with the incre ase in the strength of the modulating potential, the freezing transiti on changes from a first order to a continuous one via a tricritical po int for a suitable choice of the modulating wavevectors. We demonstrat e here that the continuous nature of the freezing transition at large values of the external potential V-e survives the presence of fluctuat ions. We also show that fluctuations tend to stabilize the liquid phas e in the large V-e regime.