HIGHLY CIS-SELECTIVE HORNER-WADSWORTH-EMMONS (HWE) REACTION OF METHYLBIS(2,4-DIFLUOROPHENYL)PHOSPHONOACETATE

Authors
KOKIN K MOTOYOSHIYA J HAYASHI S AOYAMA H
Citation
K. Kokin et al., HIGHLY CIS-SELECTIVE HORNER-WADSWORTH-EMMONS (HWE) REACTION OF METHYLBIS(2,4-DIFLUOROPHENYL)PHOSPHONOACETATE, Synthetic communications, 27(14), 1997, pp. 2387-2392
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
27
Issue
14
Year of publication
1997
Pages
2387 - 2392
Database
ISI
SICI code
0039-7911(1997)27:14<2387:HCH(RO>2.0.ZU;2-5
Abstract
Of the previously reported Horner-Wadsworth-Emmons (HWE) reaction, the olefination of methyl bis(2,4-difluorophenyl)phosphonoacetate (la) wi th various aldehydes gave unsaturated esters in the highest cis-select ivity.