SIMULTANEOUS MULTISPECTRAL IMAGING IN THE VISIBLE AND NEAR-INFRARED REGION - APPLICATIONS IN DOCUMENT AUTHENTICATION AND DETERMINATION OF CHEMICAL INHOMOGENEITY OF COPOLYMERS
Cd. Tran et al., SIMULTANEOUS MULTISPECTRAL IMAGING IN THE VISIBLE AND NEAR-INFRARED REGION - APPLICATIONS IN DOCUMENT AUTHENTICATION AND DETERMINATION OF CHEMICAL INHOMOGENEITY OF COPOLYMERS, Analytical chemistry (Washington), 70(22), 1998, pp. 4701-4708
A new multispectral imaging spectrometer capable of simultaneously rec
ording spectral images in the visible and near-infrared has been devel
oped. In this instrument, an acoustooptic tunable filter is used to di
ffract an unpolarized incident light into two diffracted beams with or
thogonal polarization; one of them is detected by a silicon camera for
the visible region while the other beam is detected in the near-infra
red region (li om I to 1.7 mu m) with a NIR camera. The imaging spectr
ometer is sensitive, inexpensive, and field deployable because it is b
ased on the recently available InGaAs focal plane arrays camera, which
is low cost and can be sensitively operated at room temperature. Prel
iminary applications of the imaging spectrometer include measurements
of the visible and NIR absorption spectra of ink used to print U.S. cu
rrency. Such results may help to characterize samples as well as to co
ntrol and to ensure the quality of the samples during the production p
rocesses; More important are the results obtained on ethylene/vinyl ac
etate copolymers. The NIR spectral images obtained clearly indicate th
at these copolymers exhibit a high degree of chemical inhomogeneity. B
ecause of the possibility of inhomogeneity, it is very important that
the homogeneity of polymers or copolymers be thoroughly understood bef
ore the NIR methods, especially those based on NIR spectrometers equip
ped with a single-element detector, are used for measurements.