A VERSATILE COPPER-INDUCED SYNTHESIS OF FLUORINATED OLIGO(PARA-PHENYLENES)

Authors
BABUDRI F CARDONE A FARINOLA GM NASO F
Citation
F. Babudri et al., A VERSATILE COPPER-INDUCED SYNTHESIS OF FLUORINATED OLIGO(PARA-PHENYLENES), Tetrahedron, 54(48), 1998, pp. 14609-14616
Citations number
34
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
54
Issue
48
Year of publication
1998
Pages
14609 - 14616
Database
ISI
SICI code
0040-4020(1998)54:48<14609:AVCSOF>2.0.ZU;2-0
Abstract
Ullmann-like reductive coupling of 1,4-diiodo-2,3,5,6-tetrafluorobenze ne, promoted by copper(I) thiophene-2-carboxylate in N-methylpyrrolidi none at room temperature, followed by treatment with lithium aluminum hydride in THF, allowed us to obtain fluorinated poly(para-phenylene) oligomers containing up to five aromatic rings with hydrogen atoms as terminal groups. (C) 1998 Elsevier Science Ltd. All rights reserved.