ASYMMETRIC ETHYLMAGNESIATION OF ALKENES USING A NOVEL ZIRCONIUM CATALYST

Authors
BELL L BROOKINGS DC DAWSON GJ WHITBY RJ RAYMOND VH MICHAEL CH
Citation
L. Bell et al., ASYMMETRIC ETHYLMAGNESIATION OF ALKENES USING A NOVEL ZIRCONIUM CATALYST, Tetrahedron, 54(48), 1998, pp. 14617-14634
Citations number
69
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
54
Issue
48
Year of publication
1998
Pages
14617 - 14634
Database
ISI
SICI code
0040-4020(1998)54:48<14617:AEOAUA>2.0.ZU;2-R
Abstract
The novel C-1-symmetric zirconocene CpCpZrCl2 (Cp=C5H5, Cp*=1-neoment hyl-4, 5, 6, 7-tetrahydroindenyl) is a cheap, active, and effective ca talyst for the asymmetric ethylmagnesiation of unactivated terminal al kenes. (C) 1998 Elsevier Science Ltd. All rights reserved.