IRON(II)-8-QUINOLINOL MCM-41-CATALYZED PHENOL HYDROXYLATION AND REACTION-MECHANISM/

Authors
LIU CB SHAN YJ YANG XG YE XK WU Y
Citation
Cb. Liu et al., IRON(II)-8-QUINOLINOL MCM-41-CATALYZED PHENOL HYDROXYLATION AND REACTION-MECHANISM/, Journal of catalysis, 168(1), 1997, pp. 35-41
Citations number
33
Categorie Soggetti
Chemistry Physical
Journal title
Journal of catalysis → ACNP
ISSN journal
00219517
Volume
168
Issue
1
Year of publication
1997
Pages
35 - 41
Database
ISI
SICI code
0021-9517(1997)168:1<35:IMPHAR>2.0.ZU;2-P
Abstract
Iron(II)-8-quinolino/MCM-41 is prepared. Its catalysis is studied in p henol hydroxylation using H2O2 (30%) as oxidant. The experiment shows that Iron(II)-8-quinolinol/MCM-41 has good catalytic activity and desi red stability. Based on cyclic voltammetry, ESR, and UV-visible spectr a studies of iron(II)-8-quinolinol complex in liquid phase, a radical substitution mechanism is proposed and used to demonstrate the experim ental facts clearly. (C) 1997 Academic Press.