TRANSITION-METAL TEMPLATE SYNTHESIS OF A ROTAXANE INCORPORATING 2 DIFFERENT COORDINATING UNITS IN ITS THREAD

Authors
GAVINA P SAUVAGE JP
Citation
P. Gavina et Jp. Sauvage, TRANSITION-METAL TEMPLATE SYNTHESIS OF A ROTAXANE INCORPORATING 2 DIFFERENT COORDINATING UNITS IN ITS THREAD, Tetrahedron letters, 38(20), 1997, pp. 3521-3524
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
20
Year of publication
1997
Pages
3521 - 3524
Database
ISI
SICI code
0040-4039(1997)38:20<3521:TTSOAR>2.0.ZU;2-V
Abstract
A [2]rotaxane consisting of a molecular string threaded into a coordin ating ring by means of the template effect of copper (I) has been synt hesized. The acyclic fragment incorporates two different chelating sit es (bidentate and terdentate ligands) whereas the macrocycle bears a b identate chelate. Two bulky groups have been covalently attached at th e ends of the thread. (C) 1997 Elsevier Science Ltd.