INITIAL STATES OF EPITAXIAL-GROWTH OF VANADYL-PHTHALOCYANINE AND TITANYL-PHTHALOCYANINE ON MOS2 CLEAVED SURFACES

The initial states of epitaxial growth of vanndyl-phthalocyanine (VOPc ) and titanyl-phthalocyanine (TiOPc) on MoS2 cleaved surfaces have bee n investigated, using atomic force microscopy (AFM) and electron energ y loss spectroscopy (EELS). In the case of VOPc, formation of the firs t layer at room temperature which consists of one molecular layer on a MoS2 surface was observed in thr AFM image. In the case elf TiOPc. in contrast, the first layer consisted of two molecular layers formed at room temperature, and the formation of one molecular layer occurred a t the annealing at 420 K. These results indicate that the interaction between the VOPc molecule and the MoS2 surface is stronger than that b etween TiOPc and MoS2. This suggests that the overlap of orbitals of t he transition metals at the center of the phthalocyanines with the orb itals of MoS2 substrate creates a large stabilization energy. The resu lts of EELS measurement indicate that the molecular plane of VOPc is p arallel to the MoS2 surface, while the molecular plane of TiOPc is inc lined. (C) 1998 Published by Elsevier Science Ltd. All rights reserved .