The determination of impact sensitivity of high explosives (HE) is the
most commonly used way of evaluating an explosive hazard. Because of
the diversity of practical conditions that make an explosion possible,
many experimental methods for measuring sensitivity have been develop
ed. Therefore, the prediction of sensitivity to impact of energetic ma
terials is essential. This work discusses a criterion that aids in suc
h screening for all families of energetic substances. This criterion i
s based on the maximum heat of reaction. The results of our research r
eveal a satisfactory mutual interfamily relation between both the theo
retical criterion of sensitivity (CS) and experimental values.