ON THE FORMATION OF OXYGENATED PRODUCTS BY CO HYDROGENATION WITH LANTHANA PROMOTED RHODIUM CATALYSTS

Citation
P. Gronchi et al., ON THE FORMATION OF OXYGENATED PRODUCTS BY CO HYDROGENATION WITH LANTHANA PROMOTED RHODIUM CATALYSTS, Reaction kinetics and catalysis letters, 60(1), 1997, pp. 79-88
Citations number
11
Categorie Soggetti
Chemistry Physical
ISSN journal
01331736
Volume
60
Issue
1
Year of publication
1997
Pages
79 - 88
Database
ISI
SICI code
0133-1736(1997)60:1<79:OTFOOP>2.0.ZU;2-W
Abstract
La2O3 with Rh based catalysts, has a promoting effect on the carbon ef ficiencies of C1 and C2 oxygenated products. CO2 seems specifically in volved in the reaction pathway. Its formation and activation may indee d lead to stabilized undissociated CO (stabilized acyl group) which ev olves further to oxygenated products (ethanol).