PALLADIUM ACTIVITY IN 3-THIOLENE-1,1-DIOXIDE HYDROGENATION IN THE PRESENCE OF ALKALIS

Authors
MASHKINA AV YAKOVLEVA VN VOSKRESENSKAYA TP
Citation
Av. Mashkina et al., PALLADIUM ACTIVITY IN 3-THIOLENE-1,1-DIOXIDE HYDROGENATION IN THE PRESENCE OF ALKALIS, Reaction kinetics and catalysis letters, 60(1), 1997, pp. 157-162
Citations number
9
Categorie Soggetti
Chemistry Physical
Journal title
Reaction kinetics and catalysis letters → ACNP
ISSN journal
01331736
Volume
60
Issue
1
Year of publication
1997
Pages
157 - 162
Database
ISI
SICI code
0133-1736(1997)60:1<157:PAI3HI>2.0.ZU;2-V
Abstract
Metallic palladium supported on gamma-Al2O3 exhibits low activity in 3 -thiotene-1,1-dioxide hydrogenation in alkaline alcohol solutions. It converts the above thiolene to 3-alkoxy-thiolane-1,1-dioxide, which is hydrogenated to thiolane-1,1-dioxide, at elevated temperatures favori ng Pd sulfurization to PdS.