ON THE MECHANISM OF THE FORMATION OF DIHYDROFURYL RADICALS IN THE CDS-CATALYZED PHOTOADDITION OF 2,5 DIHYDROFURAN TO AZOBENZENE

Authors
REINHEIMER A KISCH H
Citation
A. Reinheimer et H. Kisch, ON THE MECHANISM OF THE FORMATION OF DIHYDROFURYL RADICALS IN THE CDS-CATALYZED PHOTOADDITION OF 2,5 DIHYDROFURAN TO AZOBENZENE, Journal of information recording, 24(3-4), 1998, pp. 211-215
Citations number
12
Categorie Soggetti
Photographic Tecnology","Material Science
Journal title
Journal of information recording → ACNP
ISSN journal
10256008
Volume
24
Issue
3-4
Year of publication
1998
Pages
211 - 215
Database
ISI
SICI code
1025-6008(1998)24:3-4<211:OTMOTF>2.0.ZU;2-V
Abstract
The photoaddition of 2,5-dihydrofuran to azobenzene is known to afford the corresponding allylhydrazine (type B semiconductor photocatalysis ). In this investigation it was found that the intermediate dihydrofur yl radical is formed through a dissociative electron transfer to the r eactive valence band hole.