REGIOSELECTIVE PHOTOACYLATION OF SUBSTITUTED NAPHTHOQUINONES

Citation
C. Schiel et al., REGIOSELECTIVE PHOTOACYLATION OF SUBSTITUTED NAPHTHOQUINONES, Journal of information recording, 24(3-4), 1998, pp. 257-260
Citations number
5
Categorie Soggetti
Photographic Tecnology","Material Science
ISSN journal
10256008
Volume
24
Issue
3-4
Year of publication
1998
Pages
257 - 260
Database
ISI
SICI code
1025-6008(1998)24:3-4<257:RPOSN>2.0.ZU;2-#
Abstract
Photoreactions of aldehydes with quinones exhibit acylated hydroquinon es in good yields. In the case of substituted naphthoquinones (pos. 5- 8) two regioisomers are formed. However, lithium perchlorate as additi ve affords only one regioisomer. This effect is discussed on the basis of semiempirical calculations.