PET-OXIDATIVE REACTIONS OF SILOXY-CYCLOPROPANES

Authors
RINDERHAGEN H MATTAY J
Citation
H. Rinderhagen et J. Mattay, PET-OXIDATIVE REACTIONS OF SILOXY-CYCLOPROPANES, Journal of information recording, 24(3-4), 1998, pp. 261-264
Citations number
7
Categorie Soggetti
Photographic Tecnology","Material Science
Journal title
Journal of information recording → ACNP
ISSN journal
10256008
Volume
24
Issue
3-4
Year of publication
1998
Pages
261 - 264
Database
ISI
SICI code
1025-6008(1998)24:3-4<261:PROS>2.0.ZU;2-7
Abstract
The oxidative reaction of 1-trimethysiloxy-cyclopropanes has been inve stigated under PET conditions. The mechanism could be partially elucid ated concerning the first reaction steps. The equilibrium of the mutua l rearranging exo- and endo- radicals is determined by ring strain and radical-stability.