BIOMIMETIC MODELS BASED ON RU-POLYPURIDINE-COMPLEXES - ELECTRON-TRANSFER IN SUPRAMOLECULAR ASSEMBLIES

Authors
DAVID E VANLOYEN D BORN R BOSSMANN S DURR H WILLNER I
Citation
E. David et al., BIOMIMETIC MODELS BASED ON RU-POLYPURIDINE-COMPLEXES - ELECTRON-TRANSFER IN SUPRAMOLECULAR ASSEMBLIES, Journal of information recording, 24(3-4), 1998, pp. 277-284
Citations number
15
Categorie Soggetti
Photographic Tecnology","Material Science
Journal title
Journal of information recording → ACNP
ISSN journal
10256008
Volume
24
Issue
3-4
Year of publication
1998
Pages
277 - 284
Database
ISI
SICI code
1025-6008(1998)24:3-4<277:BMBOR->2.0.ZU;2-S
Abstract
Natural 1, 3 and nonnatural 2, 4 models for the photosynthetic reactio n center based on RuL2L'- and RuL3- complexes were prepared. Photophys ical studies with static and time resolved spectroscopy demonstrated a clear noncovalent interaction between 1-4 and the acceptor BXV4+, bei ng dominant in the complexes 3 and 4 having two binding sites per bran ch. The results were supported by NMR experiments.