P-H BOND ACTIVATION AT A TUNGSTEN(0) CENTER - SYNTHESIS AND CHARACTERIZATION OF WH(PPH2)(DPPE)(2)

Authors
FIELD LD JONES NG TURNER P
Citation
Ld. Field et al., P-H BOND ACTIVATION AT A TUNGSTEN(0) CENTER - SYNTHESIS AND CHARACTERIZATION OF WH(PPH2)(DPPE)(2), Journal of organometallic chemistry, 571(2), 1998, pp. 195-199
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
571
Issue
2
Year of publication
1998
Pages
195 - 199
Database
ISI
SICI code
0022-328X(1998)571:2<195:PBAAAT>2.0.ZU;2-9
Abstract
Irradiation of the dinitrogen complex W(N-2)(2)(dppe)(2) 1 [dppe = bis -1,2-(diphenylphosphino)ethane] in the presence of diphenylphosphine r esults in P-H bond activation to give the phosphido complex WH(Ph-2)(d ppe)(2) 2. The X-ray crystal structure of the phosphido complex 2 indi cates a W-P bond length of 2.28 Angstrom that is consistent with a W-P double bond. (C) 1998 Elsevier Science S.A. All rights reserved.