PHOTOCHEMICAL-SYNTHESIS OF NOVEL OXYGEN-TRANSFER REAGENTS

Authors
SANDER W KIRSCHFELD A MUTHUSAMY S SCHROEDER K KAPPERT W
Citation
W. Sander et al., PHOTOCHEMICAL-SYNTHESIS OF NOVEL OXYGEN-TRANSFER REAGENTS, Journal of information recording, 24(5-6), 1998, pp. 349-356
Citations number
25
Categorie Soggetti
Photographic Tecnology","Material Science
Journal title
Journal of information recording → ACNP
ISSN journal
10256008
Volume
24
Issue
5-6
Year of publication
1998
Pages
349 - 356
Database
ISI
SICI code
1025-6008(1998)24:5-6<349:PONOR>2.0.ZU;2-I
Abstract
Pure crystalline dimesityldioxirane has been synthesized on a preparat ive scale by photooxidation of dimesityl diazomethane with filtered li ght in solution at low temperature. The synthetic procedure is a scale d-up version of a reaction path which has previously been observed in inert matrices. Mechanistic details of the reaction in solution and st ructural and spectroscopic properties of the dioxirane, as well as exa mples of its utilization as an oxidizing reagent are described.