We find a new representation of the simple Lie algebra of type E 6 on the polynomial algebra in 16 variables, which gives a fractional representation of the corresponding Lie group on 16-dimensional space. Using this representation and Shen.s idea of mixed product, we construct a new functor from D 5-Mod to E 6-Mod. A condition for the functor to map a finite-dimensional irreducible D 5-module to an infinite-dimensional irreducible E 6-module is obtained. Our results yield explicit constructions of certain infinite-dimensional irreducible weight E6-modules with finite-dimensional weight subspaces. In our approach, the idea of Kostant.s characteristic identities plays a key role.