In this paper, we study solution structures of the following generalized Lennard-Jones system in .n, x.=(..|x|.+2+.|x|.+2)x , with 0 < . < .. Considering periodic solutions with zero angular momentum, we prove that the corresponding problem degenerates to 1-dimensional and possesses infinitely many periodic solutions which must be oscillating line solutions or constant solutions. Considering solutions with non-zero angular momentum, we compute Morse indices of the circular solutions first, and then apply the mountain pass theorem to show the existence of non-circular solutions with non-zero topological degrees. We further prove that besides circular solutions the system possesses in fact countably many periodic solutions with arbitrarily large topological degree, infinitely many quasi-periodic solutions, and infinitely many asymptotic solutions.