SYNTHESIS AND CHARACTERIZATION OF TETRAPHENYLPHOSPHONIUM HALOCHROMATES

Authors
PATNAIK U MURALIDHAR J
Citation
U. Patnaik et J. Muralidhar, SYNTHESIS AND CHARACTERIZATION OF TETRAPHENYLPHOSPHONIUM HALOCHROMATES, JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 53(3), 1998, pp. 817-824
Citations number
18
Categorie Soggetti
Chemistry Analytical","Chemistry Physical
Journal title
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
ISSN journal
13886150 → ACNP
Volume
53
Issue
3
Year of publication
1998
Pages
817 - 824
Database
ISI
SICI code
0368-4466(1998)53:3<817:SACOTH>2.0.ZU;2-Y
Abstract
Ion-associated halochromates (halo = F, Cl, Br) from tetraphenylphosph onium cation (Ph4P+) are synthesized by stepwise solvent extraction te chnique and characterized based on XRD, spectral and thermal studies. The Ph4P+CrO3B- crystal is tetragonal with a=b=12.368 and c=7.511 Angs trom. Thermal stabilities of these complexes are found to be decreasin g in the order of Ph4P+CrO3F- > Ph4P+CrO3Cl- > Ph4P+CrO3Br-.