Ls. Puckhaber et al., KENAF PHYTOALEXIN - TOXICITY OF O-HIBISCANONE AND ITS HYDROQUINONE TOTHE PLANT-PATHOGENS VERTICILLIUM-DAHLIAE AND FUSARIUM-OXYSPORUM F SP.VASINFECTUM, Journal of agricultural and food chemistry, 46(11), 1998, pp. 4744-4747
o-Hibiscanone (HBQ) is a phytoalexin produced by kenafin response to i
nfection by the wilt pathogen Verticillium dahliae. In several bioassa
ys utilizing both conidia and mycelia of V. dahliae, HBQ was significa
ntly more toxic than desoxyhemigossypol, the most; potent phytoalexin
produced by cotton. HBQ also was more toxic to conidia of Fusarium oxy
sporum f, sp. vasinfectum. C-13-NMR experiments revealed that HBQ is r
educed to its hydroquinone by V. dahliae conidia. Bioassays of HBQ and
its hydroquinone established that the quinone is considerably more to
xic to V. dahliae than is the hydroquinone. This biotransformation app
arently represents a detoxification mechanism employed by the pathogen
.