ASYMMETRIC BAYLIS-HILLMAN REACTIONS - CATALYSIS USING A CHIRAL PYRROLIZIDINE BASE

Citation
Agm. Barrett et al., ASYMMETRIC BAYLIS-HILLMAN REACTIONS - CATALYSIS USING A CHIRAL PYRROLIZIDINE BASE, Chemical communications, (22), 1998, pp. 2533-2534
Citations number
15
Categorie Soggetti
Chemistry
Journal title
ISSN journal
13597345
Issue
22
Year of publication
1998
Pages
2533 - 2534
Database
ISI
SICI code
1359-7345(1998):22<2533:ABR-CU>2.0.ZU;2-F
Abstract
A novel chiral pyrrolizidine base 5 derived from L-proline promotes th e Baylis-Hillman reaction of ethyl and methyl vinyl ketones with elect ron deficient aromatic aldehydes with moderate levels of enantiomeric excess.