TRAPPING OF N-BUTYLLITHIUM DIMER BY A TRILITHIATED DERIVATIVE OF (AL[N(H)BU-T](3))(2)

Authors
BRASK JK CHIVERS T YAP GPA
Citation
Jk. Brask et al., TRAPPING OF N-BUTYLLITHIUM DIMER BY A TRILITHIATED DERIVATIVE OF (AL[N(H)BU-T](3))(2), Chemical communications, (22), 1998, pp. 2543-2544
Citations number
20
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
22
Year of publication
1998
Pages
2543 - 2544
Database
ISI
SICI code
1359-7345(1998):22<2543:TONDBA>2.0.ZU;2-E
Abstract
The reaction of {Al[N(H)Bu-t](3)}(2), obtained as a 1 : 2 mixture of c is and trans isomers from the addition of AlCl3 to three equiv. LiN(H) Bu-t in diethyl ether, with LiBun generates a complex in which a dimer ic n-butyllithium fragment is trapped by the trilithiated derivative L i3Al2[N(H)Bu-t](3)[N-Bu-t](3).