An analysis has been carried out of the effects of energetic electron
precipitation (EEP) on stratospheric NOy, NO2, and O-3. Solar wind obs
ervations used together with precipitating electron fluxes observed ab
oard TIROS spacecraft show a close relationship between the long- and
short-term fluctuations in the solar wind and EEP over a period of 16
years. Daily electron energy spectra for 4.25 less than or equal to E
less than or equal to 1050 keV and energy deposition profiles are deve
loped for both hemispheres for L greater than or equal to 5 and used i
n two-dimensional chemical transport simulations for the period Januar
y 15, 1979, through December 31, 1987. Results indicate that globally
averaged column NOy (from 25 to 40 km) increases by approximate to 12%
between 1979 and 1983-1985 with a rapid decline to 1979 levels betwee
n early 1985 and 1987. Day-by-day comparisons of the results with the
Stratospheric Aerosol and Gas Experiment (SAGE II) column NO2 and O-3
for the period October 24, 1984, and December 31, 1987, show good agre
ement with the inclusion of EEP in the simulations. Northern near-hemi
spheric decreases of column NO2 of approximate to 35% observed by SAGE
II between early 1985 and 1987 are well simulated with the inclusion
of EEP. Comparisons of several simulations with one another and with S
AGE II: NO2 data and Solar Backscattered Ultraviolet (SBUV) (V6) O-3 d
ata suggest that SOLACE represents a solar- terrestrial coupling mecha
nism which, for solar cycle 21, is as important to stratospheric O-3 a
s solar UV flux variations.