HIGH-PRESSURE ASSISTED 1,3-DIPOLAR CYCLOADDITIONS - FORMATION OF 1,2,3-TRIAZOLES FROM ARYL AZIDES AND (TRIMETHYLSILYL)ACETYLENE

Authors
MELAI V BRILLANTE A ZANIRATO P
Citation
V. Melai et al., HIGH-PRESSURE ASSISTED 1,3-DIPOLAR CYCLOADDITIONS - FORMATION OF 1,2,3-TRIAZOLES FROM ARYL AZIDES AND (TRIMETHYLSILYL)ACETYLENE, Journal of the Chemical Society. Perkin transactions. II (Print), (11), 1998, pp. 2447-2449
Citations number
17
Categorie Soggetti
Chemistry Physical","Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Perkin transactions. II (Print) → ACNP
ISSN journal
03009580
Issue
11
Year of publication
1998
Pages
2447 - 2449
Database
ISI
SICI code
0300-9580(1998):11<2447:HA1C-F>2.0.ZU;2-Z
Abstract
The cycloaddition of aryl azides to the corresponding 1,2,3-triazoles has been studied by means of FTIR spectroscopy in a diamond anvil cell at pressures up to 1 GPa. The rate of reaction increases logarithmica lly with pressure and the yield is close to quantitative.