Th. Ko et Ws. Kuo, EFFECT OF CARBON FABRIC TYPE ON THE MECHANICAL PERFORMANCE OF 2D CARBON CARBON COMPOSITES/, Polymer composites, 19(5), 1998, pp. 618-625
A stabilized PAN fabric was carbonized and graphitized from 800 degree
s C to 2500 degrees C. Two-dimensional (2D) carbon/carbon composites w
ere made using the stabilized PAN fabric, carbonized fabrics, and a re
sol-type phenol-formaldehyde resin. These composites were heat-treated
from 600 degrees C to 2500 degrees C. The influence of different heat
-treated fabrics and heat treatments on the fracture and flexural stre
ngth of these composites was also studied. The composite reinforced wi
th higher heat-treated fabrics showed a lower weight loss than that wi
th lower heat-treated fabrics. When the composites were graphitized at
2500 degrees C, the loss was 49.7 wt% for the composite made with sta
bilized PAN fabric and 26 wt% for that with carbonized fabric at 2500
degrees C. Those composites also have a higher density than composites
produced by other methods. Composites made with stabilized PAN fabric
exhibited a strong bonding in the fiber/matrix during pyrolysis. This
composite showed catastrophic fracture and a smooth fracture surface
with no fiber pullout. Composites made with higher carbonized fabrics
exhibited a weak interface bonding. These composites showed a pseudo-p
lastic fracture pattern with fiber pullout during pyrolysis. Composite
s made with carbonized fabrics at 2000 degrees C and 2500 degrees C sh
owed the highest flexural strength at the prolysis temperature of 1000
degrees C. Composites made with carbonized fabric at 1300 degrees C s
howed the highest flexural strength above 1500 degrees C to 2500 degre
es C. The composite made with stabilized PAN fabric exhibited the lowe
st flexural strength during pyrolysis.