In Er-doped silicon we have found direct evidence for the formation of
the Er-related intermediate state that is a precursor of the final 4f
-electron excited state responsible fur the 0.8 eV luminescence. Time-
resolved photoluminescence following band-gap illumination shows disru
ption of this center by a THz pulse from a free-electron laser. The de
cay of the intermediate state could be directly monitored in this doub
le-beam experiment and a lifetime of approximately 100 mu s has been f
ound. Tn this way the most characteristic step in die excitation mecha
nism of the Er ion in silicon has been revealed experimentally. [S0031
-9007(98)07761-8].