STOICHIOMETRIC AND CATALYTIC ACTIVATION OF ALLYLDIMETHYLSILANE - SYNTHESIS OF [RUH2(ETA(4)-HSIME2(CH=CHME))(PCY3)(2)]

Authors
DELPECH F SABOETIENNE S DONNADIEU B CHAUDRET B
Citation
F. Delpech et al., STOICHIOMETRIC AND CATALYTIC ACTIVATION OF ALLYLDIMETHYLSILANE - SYNTHESIS OF [RUH2(ETA(4)-HSIME2(CH=CHME))(PCY3)(2)], Organometallics, 17(23), 1998, pp. 4926-4928
Citations number
27
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
17
Issue
23
Year of publication
1998
Pages
4926 - 4928
Database
ISI
SICI code
0276-7333(1998)17:23<4926:SACAOA>2.0.ZU;2-N
Abstract
The bis(dihydrogen)ruthenium complex RuH2(H-2)(2)(PCy3)(2) (1) reacts with (CH2=CHCH2)Me2SiH to produce the title complex 4, a very reactive species stabilized by coordination of a vinylsilane ligand via Ru-(et a(2)-H-Si) and Ru-(eta(2)-C=C) bonds. 4 catalyzes silylation of (CH2=C HCH2)Me2SiH and redistribution at silicon render C2H4 pressure.