THE KINETIC-STUDY ON THE ELECTROLYTIC HYDROGENATION OF NITROBENZENE ON THE HYDROGEN-STORAGE ALLOY ELECTRODE

Citation
Sg. Lu et al., THE KINETIC-STUDY ON THE ELECTROLYTIC HYDROGENATION OF NITROBENZENE ON THE HYDROGEN-STORAGE ALLOY ELECTRODE, Journal of electroanalytical chemistry [1992], 457(1-2), 1998, pp. 149-153
Citations number
7
Categorie Soggetti
Electrochemistry,"Chemistry Analytical
Journal title
Journal of electroanalytical chemistry [1992]
ISSN journal
15726657 → ACNP
Volume
457
Issue
1-2
Year of publication
1998
Pages
149 - 153
Database
ISI
SICI code
Abstract
The electrolytic hydrogenation of nitrobenzene (NB) was studied by mea ns of a hydrogen-storage alloy electrode. It has been found that hydro gen-storage alloy is an effective electrode for the conversion of nitr obenzene to aniline. The aniline yield and average current efficiency can reach 90%. The beta hydride phase shows catalytic activity for the electrolytic hydrogenation of nitrobenzene, mainly resulting from its ample absorbed hydrogen atoms and favorable structure. (C) 1998 Elsev ier Science S.A. All rights reserved.