REACTION OF ALPHA-HYDROXYAMINO KETONES WITH DICARBONYL-COMPOUNDS - SYNTHESIS OF IMIDAZOLINE NITROXIDES WITH A FUNCTIONAL-GROUP IN A SIDE-CHAIN

Authors
REZNIKOV VA VOLODARSKY LB
Citation
Va. Reznikov et Lb. Volodarsky, REACTION OF ALPHA-HYDROXYAMINO KETONES WITH DICARBONYL-COMPOUNDS - SYNTHESIS OF IMIDAZOLINE NITROXIDES WITH A FUNCTIONAL-GROUP IN A SIDE-CHAIN, Liebigs Annalen, (5), 1997, pp. 1035-1040
Citations number
14
Categorie Soggetti
Chemistry
Journal title
Liebigs Annalen → ACNP
ISSN journal
09473440
Issue
5
Year of publication
1997
Pages
1035 - 1040
Database
ISI
SICI code
0947-3440(1997):5<1035:ROAKWD>2.0.ZU;2-V
Abstract
The reaction of alpha-hydroxyamino ketones 1 with diacetyl, acetyl ace tone or acetoacetic ester in the presence of ammonium acetate results in the formation of 3-imidazoline derivatives 2, which are precursors for the synthesis of stable nitroxides 8, 9, 14, 16, 17, 23-24 with va rious functional groups in the side chain at the 2-position of the het erocycle.