MICROSTRUCTURED POROUS SILICA OBTAINED VIA COLLOIDAL CRYSTAL TEMPLATES

A novel scheme for using modified colloidal crystals as templates for silica polymerization is reported. 3D close-packed crystals of submicr ometer latex spheres are assembled on a membrane surface by filtration . To induce silica polymerization, the particles are modified by adsor ption of the surfactant hexadecyltrimethylammonium bromide. The colloi dal crystals are then infused with a silica solution, which polymerize s in the cavities. In the final stage, the latex particles are removed by calcination, leaving behind porous silica of very low density. Sca nning electron microscopy images demonstrate that the product has high ly uniform sind structured pores, representing a negative replica of t he original colloidal crystal. The size of the pores can be controlled by changing the size of the latex used, and we were able to obtain sa mples with pores ranging from 150 to 1000 nm. Thus the method allows o ne to obtain structured silica materials of which the pore size, shape , and ordering can be controlled in a wide region that has previously been unattainable.