A NOVEL PHOTOCHEMICAL-SYNTHESIS OF DIDEOXYFURANOSYL DISACCHARIDES

Authors
ANGELINI MP LEERUFF E
Citation
Mp. Angelini et E. Leeruff, A NOVEL PHOTOCHEMICAL-SYNTHESIS OF DIDEOXYFURANOSYL DISACCHARIDES, Tetrahedron letters, 39(48), 1998, pp. 8783-8786
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
48
Year of publication
1998
Pages
8783 - 8786
Database
ISI
SICI code
0040-4039(1998)39:48<8783:ANPODD>2.0.ZU;2-6
Abstract
A photochemical glycosylation is described using the chiral cyclobutan one 1. Irradiation of ketone 1 in me presence of monosaccharides 2 and 3 gives photoadducts derived from OH insertion of the transient carbe ne. The carbene inserts into the N-H group in the case of nucleoside 4 . (C) 1998 Elsevier Science Ltd. All rights reserved.