VINYLALUMINATION OF FLUORO-CARBONYL COMPOUNDS

Authors
RAMACHANDRAN PV REDDY MVR RUDD MT DEALANIZ JR
Citation
Pv. Ramachandran et al., VINYLALUMINATION OF FLUORO-CARBONYL COMPOUNDS, Tetrahedron letters, 39(48), 1998, pp. 8791-8794
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
48
Year of publication
1998
Pages
8791 - 8794
Database
ISI
SICI code
0040-4039(1998)39:48<8791:VOFC>2.0.ZU;2-5
Abstract
Ethyl acrylate and acrylonitrile fail to undergo efficient Baylis-Hill man reaction with fluoral, but provide good yields of products with pe ntafluorobenzaldehyde. Alternately, unsubstituted and beta-substituted [alpha- (ethoxycarbonyl)vinyl]aluminum react with perfluoroalkyl and -aryl aldehydes and ketones to provide the alpha-hydroxyalkenylated fl uoroorganic compounds in good to excellent yields. (C) 1998 Elsevier S cience Ltd. All rights reserved.