CONDENSATION OF ALLYL ALCOHOL WITH AMMONIA OVER PHOSPHORIC-ACID CATALYST SUPPORTED ON CONTROLLED-PORE GLASS

Citation
S. Gobolos et al., CONDENSATION OF ALLYL ALCOHOL WITH AMMONIA OVER PHOSPHORIC-ACID CATALYST SUPPORTED ON CONTROLLED-PORE GLASS, Applied catalysis. A, General, 152(1), 1997, pp. 63-68
Citations number
5
Categorie Soggetti
Chemistry Physical","Environmental Sciences
ISSN journal
0926860X
Volume
152
Issue
1
Year of publication
1997
Pages
63 - 68
Database
ISI
SICI code
0926-860X(1997)152:1<63:COAAWA>2.0.ZU;2-2
Abstract
The condensation of allyl alcohol with ammonia was studied over phosph oric acid catalyst supported on controlled pore glass (CPG). The above catalyst was compared with silica supported phosphoric acid. The CPG supported catalyst showed higher selectivity and lower rate of deactiv ation than the corresponding silica supported one. The above differenc e can be attributed to both the boron content and the large pore size of the CPG support.