Y. Yasutomi et al., MECHANICAL-PROPERTIES OF SIC FIBER AFTER IMMERSION IN MOLTEN ALUMINUM, Nippon Seramikkusu Kyokai gakujutsu ronbunshi, 106(11), 1998, pp. 1124-1128
Low oxygen SiC fiber/Al interfacial reactivity was evaluated in compar
ison with that of an usual Sic fiber/Al interface. Chemical compositio
n of low oxygen SiC fiber was Si:62.4, C:37.1, O:0.5 mass% and that of
a usual SiC fiber was Si : 63.7, C : 35.8, O : 12.3 mass%. The outcom
es of this study can be summarized as follows: (a) No product was dete
cted at the low oxygen SIC fiber/Al interface. (b) The low oxygen SiC
fiber-reinforced Al composite was higher corrosion resistance, and low
er strength deterioration on compared with the usual SiC fiber-reinfor
ced Al composite. (c) Al atoms diffuse into low oxygen SiC fiber. duri
ng dipping into a molten Al with the diffusivity of 6 x 10(-15) m(2)/s
. (d) In the initial stage of interfacial reaction, low oxygen SIC fib
ers are not eroded, but a needle-shape Al4C3 phase forms on the fiber
surface. On the other hand, the SiC fiber can be eroded by the Al4C3 f
ormation, when long time dipping in the molten Al under unfavorable co
nditions.