THE FIRST METAL-COMPLEX OF AN ACYCLIC HEXAPHENOL - STRUCTURE OF THE BINUCLEAR COMPLEX OF URANYL IONS WITH AN ANALOG OF P-TERT-BUTYLCALIX[6]ARENE

Citation
P. Thuery et M. Nierlich, THE FIRST METAL-COMPLEX OF AN ACYCLIC HEXAPHENOL - STRUCTURE OF THE BINUCLEAR COMPLEX OF URANYL IONS WITH AN ANALOG OF P-TERT-BUTYLCALIX[6]ARENE, Journal of the Chemical Society. Dalton transactions, (9), 1997, pp. 1481-1482
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear
ISSN journal
03009246
Issue
9
Year of publication
1997
Pages
1481 - 1482
Database
ISI
SICI code
0300-9246(1997):9<1481:TFMOAA>2.0.ZU;2-6
Abstract
The crystal structure of the bimetallic complex between uranyl ions an d the acyclic bis(hydroxymethyl)phenolic oligomer (HOCH2)[o-(p-(BuC6H2 OH)-C-t)-o-CH2](6)OH (H8L) has been determined: [(UO2)(2)(H2L)(NO3)][N Et3H](3).MeOH is the first metal complex of an acyclic analogue of a c alixarene structurally characterized.