MONONUCLEAR ZINC(II), HOMODINUCLEAR ZINC(II) AND HETERODINUCLEAR ZINC(II)-COPPER(II) COMPLEXES DERIVED FROM TRIS[(2-PYRIDYL)METHYL]AMINE

Authors
ADAMS H BAILEY NA FENTON DE HE QY
Citation
H. Adams et al., MONONUCLEAR ZINC(II), HOMODINUCLEAR ZINC(II) AND HETERODINUCLEAR ZINC(II)-COPPER(II) COMPLEXES DERIVED FROM TRIS[(2-PYRIDYL)METHYL]AMINE, Journal of the Chemical Society. Dalton transactions, (9), 1997, pp. 1533-1539
Citations number
50
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
9
Year of publication
1997
Pages
1533 - 1539
Database
ISI
SICI code
0300-9246(1997):9<1533:MZHZAH>2.0.ZU;2-R
Abstract
Mononuclear zinc(II), homodinuclear zinc(II) and heterodinuclear zinc( II)-copper(II) complexes derived from tris[(2-pyridyl)methyl]amine (L) have been prepared and characterised. The crystal structures of two m ononuclear complexes, [ZnL(Cl)][BPh4]. MeCN and [ZnL(O2CPh)][BPh4] sho w that the co-ordination geometries around the zinc lose to trigonal b ipyramidal and that of the heterodinuclear complex [ZnCuL2(p-O2NC6H4OP O3]-[BPh4](2) . H2O are 5.86 Angstrom and bridged by a phosphate monoe ster.